Reaction Pathway for Coke-Free Methane Steam Reforming on a Ni/CeO2 Catalyst: Active Sites and the Role of Metal–Support Interactions

Agustín Salcedo, Pablo G. Lustemberg, Ning Rui, Robert M. Palomino, Zongyuan Liu, Slavomir Nemsak, Sanjaya D. Senanayake, José A. Rodriguez*, M. Verónica Ganduglia-Pirovano*, Beatriz Irigoyen*

ACS Catal. 2021, 11, XXX, 8327–8337
Publication Date:June 23, 2021

"Propylene Adsorption on a Non-Stoichiometric VSbO4(110) Surface"

Hernán Seitz, Romina Luna, Alfredo Juan, Graciela Brizuela, Beatriz Irigoyen

Journal of Physical Chemistry C. ISSN: 1932-7447. 2015, 119 (9), 4967-4975.

"Density functional theory (DFT) study of H2S interactions on the Pr-doped CeO2(111) surface"

Alejandro Kinbaum, Eduardo Poggio-Fraccari, Fernando Mariño, Beatriz Irigoyen

Journal of the Argentine Chemical Society. ISSN: 1852-1207. 2017, 104(1), 34-43.

"Nickel deposition on ceria: A DFT+U study"

Dan Rajsfus, Agustín Salcedo, Brian Milberg, Beatriz Irigoyen

Journal of the Argentine Chemical Society. ISSN: 1852-1207. 2017, 104(1), 44-53.

DFT insights into structural effects of Ni-Cu/CeO2 catalysts for CO selective reaction towards water-gas shift
PHYSICAL CHEMISTRY CHEMICAL PHYSICS: ROYAL SOC CHEMISTRY. 2021 vol. 23 n° 6. p. 3826 - 3836. ISSN 1463-9076

Unraveling the Origin of Ceria Activity in Water-Gas Shift by First Principles Microkinetic Modeling
JOURNAL OF PHYSICAL CHEMISTRY C: AMER CHEMICAL SOC. 2020 vol. 124 n° 14. p. 7823 - 7834. ISSN 1932-7447

Promoted methane activation on doped ceria via occupation of Pr(4f) states
APPLIED SURFACE SCIENCE:ELSEVIER SCIENCE BV. 2018 vol. 458 p. 397 - 404. ISSN 0169-4332

Redox behavior of a low-doped Pr-CeO2(111) surface. A DFT+U study
APPLIED SURFACE SCIENCE:ELSEVIER SCIENCE BV. 2017 vol. 401 p. 206 - 217. ISSN 0169-4332

David Levitan, Abigail Rozenblit, Miguel Laborde, Pablo Giunta
Self-sustained oscillations in the potential of a CO-poisoned PEM fuel cell: A model based on physical principles
Journal of Electroanalytical Chemistry, Volume 880, 2021, 114924, ISSN 1572-6657
Abstract: A dynamic 1-D model for the simulation of the oscillatory behavior in the anode potential of a PEM fuel cell under constant current conditions and the presence of CO impurities in the H2 inlet is presented. The model is built upon electrostatic, chemical kinetic and thermodynamic principles, featuring a probabilistic treatment of dipole interactions between several chemical species in the compact layer. Model predictions are validated with available experimental data in the literature. The model is able to capture the phenomenon of the oscillatory behavior. This phenomenon occurs when the CO molar fraction in the feed exceeds 8 × 10−5. A parametric sensitivity study for CO-electrooxidation and OH-adsorption kinetic rates is also performed. The CO-electrooxidation rate has a noticeable effect on the oscillation frequency, and damped oscillations are observed for a kinetic rate of 6 × 10−3 mol m−2s−1, while OH-adsorption and desorption rates have a moderate effect on system dynamics.
Keywords: Dynamic modeling; Fuel cells; CO poisoning

Low-Cost Catalysts for the Water Gas Shift Reaction Based on Cu–Ni on La-Promoted Ceria
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY; Año: 2018 vol. 2018 p. 2865 - 2873
Flexible heat exchanger network design of an ethanol processor for hydrogen production. A model-based multi-objective optimization approach
Cu and/or Ni catalysts over CePr oxide for the water gas shift reaction: an experimental study, kinetic fitting and reactor simulation
REACTION KINETICS AND CATALYSIS LETTERS; Año: 2017 vol. 121 p. 607 - 628
Anales AFA; Lugar: Tandil; Año: 2017 vol. 28 p. 1 - 3

MARÍA LAURA DIEUZEIDE; MIGUEL LABORDE; NORMA AMADEO; C. CANNILLA; G. BONURA; F. FRUSTERI. Hydrogen Production by Glycerol Steam Reforming: How Mg doping affects the catalytic behaviour of Ni/Al2O3 catalysts. International journal of hydrogen energy. , Amsterdam: PERGAMON-ELSEVIER SCIENCE LTD, 2016 - .
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CORACH, JULIÁN; SORICHETTI, PATRICIO ANÍBAL; ROMANO, SILVIA DANIELA . Permittivity of biodiesel-rich blends with fossil diesel fuel: Application to biodiesel content estimation. Fuel. , Amsterdam: ELSEVIER SCI LTD, 2016 - .vol. 177, p. 268-273. ISSN 0016-2361.

MARÍA LAURA DIEUZEIDE; MATIAS JOBBAGY; NORMA AMADEO. Vapor-Phase Hydrogenolysis of Glycerol to 1,2-Propanediol over Cu/Al2O3 Catalyst at Ambient Hydrogen Pressure. Industrial & engineering chemical research. , Washington: AMER CHEMICAL SOC, 2016 - .vol. 55, p. 2527-2533. ISSN 0888-5885.

GONZÁLEZ-GIL, R.; HERRERA, C.; LARRUBIA, M.A.; MARIÑO, F.; LABORDE, M.; ALEMANY, L.J. . Hydrogen production by ethanol steam reforming over multimetallic RhCeNi/Al2O3 structured catalyst. Pilot-scale study. International journal of hydrogen energy. : PERGAMON-ELSEVIER SCIENCE LTD, 2016 - . vol. 41, n° 38, p. 16786-16796. ISSN 0360-3199.

MARCO OCSACHOQUE; JUAN E. RUSSMAN; BEATRIZ IRIGOYEN; DELIA GAZZOLI; M. GLORIA GONZALEZ . Experimental and theoretical study about sulfur deactivation of Ni/ CeO2 and Rh/CeO2 catalysts. Materials chemistry and physics. , Amsterdam: ELSEVIER SCIENCE SA, 2016 - . vol. 172, p. 69-76. ISSN 0254-0584.

ORIANA D'ALESSANDRO; DELFINA GARCÍA PINTOS; ALFREDO JUAN; BEATRIZ L. IRIGOYEN; JORGE SAMBETH. ADFT study of phenol adsorption on a low doping Mn-Ce composite oxide model. Applied surface science. Amsterdam: ELSEVIER SCIENCE BV, 2015 - . vol. 359, p. 14-20. ISSN 0169-4332.

IGNACIO ALLIATI; BEATRIZ IRIGOYEN . A first-principles modeling of glycerol and ammonia interactions onthe cation-deficient VSbO4(110) surface. Catalysis today. Amsterdam: ELSEVIER SCIENCE BV, 2015 - . vol. 254,p. 53-61. ISSN 0920-5861.

MARIÑO, FERNANDO J.; IGLESIAS IGNACIO; BARONETTI, GRACIELA T; ALEMANY, LUIS; LABORDE, MIGUEL. A. . Egg-shell CuO/CeO2/Al2O3catalysts for CO preferential oxidation. International journal of hydrogen energy. Amsterdam: PERGAMON-ELSEVIER SCIENCE LTD, 2015 - . vol. 40, n° 34, p. 11235-11241. ISSN 0360-3199.

CORACH, JULIÁN; SORICHETTI, PATRICIO ANÍBAL; ROMANO, SILVIA DANIELA . Electrical and ultrasonic properties of vegetable oils and biodiesel. Fuel. Amsterdam: ELSEVIER SCI LTD, 2015 - . vol. 139, p. 466-471. ISSN 0016-2361.

SIMONE M. DE REZENDE; CARLOS A. FRANCHINI; MARIA L DIEUZEIDE; ANDRÉA M. DUARTE DE FARIAS; AMADEO NORMA; MARCO A. FRAGA . Glycerol steam reforming over layered double hydroxide-supported Pt Catalysts. Chemical engineering journal. , Amsterdam: ELSEVIER SCIENCE SA, 2015 - . n° 272, p. 108-118. ISSN 1385-8947.

M.R. DÍAZ-REY; M. CORTÉS-REYES; C. HERRERA; M.A. LARRUBIA; N . AMADEO; M LABORDE; L.J. ALEMANY. Hydrogen-rich gas production from algae-biomass by lowtemperature catalytic gasification. Catalysis today.  Amsterdam: ELSEVIER SCIENCE BV, 2015 - . n° 257, p. 177-184. ISSN 0920-5861.

R. GONZÁLEZ-GIL; I. CHAMORRO-BURGOS; C. HERRERA; M.A. LARRUBIA; M. LABORDE; F. MARIÑO; L.J. ALEMANY . Production of hydrogen by catalytic steam reforming of oxygenated model compounds on Ni-modified supported catalysts. Simulation and experimental study. International journal of hydrogen energy. Amsterdam: PERGAMON-ELSEVIER SCIENCE LTD, 2015 - . vol. 40, n° 34, p. 11217-11227. ISSN 0360-3199.

ROBERT J. WESS; FEDERICO NORES PONDAL; MIGUEL A. LABORDE; PABLO D. GIUNTA . Single stage H2 production, purification and heat supply by means of Sorption-enhanced Steam Reforming of Glycerol. A thermodynamic analysis. Chemical engineering science. , Amsterdam: PERGAMON-ELSEVIER SCIENCE LTD, 2015 - . vol. 134, p. 86-95. ISSN 0009-2509.

Ce-Mn mixed oxides as supports of copper- and nickel-based catalysts for water gas shift reaction. Fuel processing technology. Eduardo Poggio Fraccari; Oriana Dalesandro; Jorge E. Sambeth; Graciela T. Baronetti; Fernando J. Mariño. Amsterdam: ELSEVIER SCIENCE BV, 2014 - . vol. 119, p. 67-73. ISSN 0378-3820.

Ce-Pr mixed oxides as active supports for Water-Gas Shift reaction: experimental and density functional theory characterization. Applied catalysis a-general. Eduardo Poggio-Fraccari; Beatriz Irigoyen; Graciela Baronetti; Fernando Mariño. Amsterdam: ELSEVIER SCIENCE BV, 2014 - . vol. 485, p. 123-132. ISSN 0926-860X.

Ce-Pr mixed oxides as active supports for Water-Gas Shift reaction: experimental and density functional theory characterization. Applied catalysis a-general. Eduardo Poggio-Fraccari; Beatriz Irigoyen; Graciela Baronetti; Fernando Mariño. Amsterdam: ELSEVIER SCIENCE BV, 2014 - . vol. 485, p. 123-132. ISSN 0926-860X.

Cu/MnOx-CeO2 and Ni/MnOx-CeO2 catalysts for the water-gas shift reaction: Metal-support interaction. International journal of hydrogen energy. Eduardo Poggio Fraccari; Jorge E. Sambeth; Graciela Baronetti; Fernando J. Mariño . Amsterdam: PERGAMON-ELSEVIER SCIENCE LTD, 2014 - . vol. 39, p. 8675-8681. ISSN 0360-3199.

Density Functional Theory study of water interactions on Mn-modified CeO2(111) surface. Applied surface science. Delfina García Pintos; Alfredo Juan; Beatriz Irigoyen. Amsterdam: ELSEVIER SCIENCE BV, 2014. vol. 313, p. 784-793. ISSN 0169-4332.

Electrical properties of vegetable oils between 20 Hz and 2 MHz. International journal of hydrogen energy. Corach, Julián; Sorichetti, Patricio Aníbal; Romano, Silvia Daniela .  Amsterdam: PERGAMON-ELSEVIER SCIENCE LTD, 2014 - . vol. 39, p. 8754-8758. ISSN 0360-3199.

Electrical properties of vegetable oils between 20 Hz and 2 MHz. International journal of hydrogen energy. Corach, J.; Sorichetti, P. A.; Romano, S. D.  Amsterdam: PERGAMON-ELSEVIER SCIENCE LTD, 2014 - . vol. 39,p. 8754-8758. ISSN 0360-3199.

Ethanol Oxidative Steam Reforming over Rh(1%)/MgAl2O4/Al2O3 Catalyst. Industrial & engineering chemical research. Cecilia Graschynsky; Amadeo Norma; LABORDE MIGUEL. Washington: AMER CHEMICAL SOC, 2014 - .vol. 53, n° 40, p. 15348-15353. ISSN 0888-5885.

Ni(II)-Mg(II)-Al(III) catalysts for hydrogen production from ethanol steam reforming: Influence of the Mg content. Applied catalysis a-general. , Adriana Romero; Matías Jobbágy; Miguel Laborde; Graciela Baronetti; Norma Amadeo. Amsterdam: ELSEVIER SCIENCE BV, 2014 - . vol. 470, p. 398-404. ISSN 0926-860X.

Self-Triggering Based on Lyapunov with Adaptive Control Law for WNCS. Ieee latin america transactions. EZEQUIEL PECKER MARCOSIG, FLAVIA FELICIONI, ANÍBAL ZANINI. New York: IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC, 2014 - . vol. 12, p. 1-7. ISSN 1548-0992.

Simulation of CO Preferential Oxidation (COPrOx) Monolithic Reactors. International journal of chemical reactor engineering. LEANDRO G. JEIFETZ; PABLO GIUNTA; FERNANDO MARIÑO; NORMA AMADEO; MIGUEL LABORDE. Berlín: BERKELEY ELECTRONIC PRESS, 2014 - . vol. 12, p. 1-12. ISSN 1542-6580.

Vanadium-Substituted Wells-Dawson Heteropolyacid as Catalyst for Liquid Phase Oxidation of 1,4-Dihydropyridine Derivative. Catalysis letters. LAURA M. SANCHEZ; ANGEL SATHICQ; GRACIELA BARONETTI; HORACIO J.THOMAS; GUSTAVO P. ROMANELLI. Berlin: SPRINGER, 2014 - . vol. 144, n° 1, p. 172-180. ISSN 1011-372X.

Vanadium-Substituted. Wells-Dawson Potassium Salt as Catalyst for Liquid phase Oxidation of 1,4-dihydropyridine Derivative. Current catalysis. LAURA M. SANCHEZ; ANGEL G. SATHICQ; GRACIELA T. BARONETTI; HORACIO J.THOMAS .Bentham, 2014 - . vol. 3, p. 147-154. ISSN 2211-5447.

Ni(II)-Al(III) layered double hydroxide as catalyst precursor for ethanol steam reforming: activation treatments and kinetic studies. Verónica Mas, María L. Dieuzeide, Matías Jobbágy1, Graciela Baronetti, Norma Amadeo, Miguel Laborde. Catalysis Today, 133-135C (2008) 319-323.

Effect of Fe doped over V-Sb oxide catalyst in toluene selective oxidation. Adriana Romero, Beatriz Irigoyen, Susana Larrondo, Silvia Jacobo, Norma Amadeo. Catalysis Today, 133-135C (2008) 775-779.

CO preferential oxidation over CuO-CeO2 catalysts synthesized by the urea thermal decomposition method. Mariño, Fernando; Schönbrod, Betina; Moreno, Máximo; Jobbagy, Matías; Baronetti, Graciela; Laborde, Miguel. Catalysis Today, 133/135 (2008) 735–742.

Optimized CuO-CeO2 catalysts for COPROX reaction. Mariño, Fernando; Baronetti, Graciela; Laborde, Miguel; Le Valant, Anthony; Bion, Nicolas; Epron, Florence; Duprez, Daniel. Int. J. Hydrogen Energy 33 (2008) 1345-1353.

Kinetics of preferential CO oxidation in H2 excess (COPROX) over CuO/CeO2 catalysts. Moreno, Máximo; Mariño, Fernando; Baronetti, Graciela; Laborde, Miguel. Int. J. Hydrogen Energy, 33 ( 2008 ) 3538 – 3542.

Ethanol steam reforming using Ni(II)-Al(III) layered double hydroxide as catalyst precursor. Kinetic  study. Mas Verónica, Baronetti Graciela, Amadeo Norma, Laborde Miguel. Chem. Eng. J.  138 (2008) 602-607.

Ethanol steam reforming on Ni/Al2O3 catalysts: Effect of Mg addition. A.J. Vizcaíno,  P. Arena, G. Baronetti, A. Carrero, J.A. Calles, M.A. Laborde, N. Amadeo. Int.  J. Hydrogen Energy 33 (2008) 3489-3492.

Hydrogen Production from Ethanol Steam Reforming: Fixed Bed Reactor Design. Giunta, Pablo; Amadeo, Norma; Laborde, Miguel. International Journal of Chemical Reactor Engineering Vol. 6: A12 (2008) Available at:

Methane partial oxidation using Ni/Ce09Zr01 O2 catalyst. S.A. Larrondo,  A. Kodjaian,  I. Fabregas,  M.G. Zimicz, D.G. Lamas, B.E. Walsoe de Reca,  N.E. Amadeo. Int. J. of Hydrogen Energy, 33 (2008) 3607-3613.

Synthesis of substituted flavones and chromones using a Wells-Dawson heteropolyacid as catalyst. Bennardi, D.O., Romanelli, G.P., Jios, J.L., Autino, J.C., Baronetti, G.T., Thomas, H.J. ARKIVOC 11 (2008) 123-130.

Direct esterification of cinnamic acids with phenols and imidoalcohols: A simple, heteropolyacid-catalyzed procedure Ruiz, D.M., Romanelli, G.P., Bennardi, D.O., Baronetti, G.T., Thomas, H.J., Autino, J.C. ARKIVOC 12 (2008) 269-276.

A simple and mild acylation of alcohols, phenols, amines, and thiols with a reusable heteropoly acid catalyst (H6P2W18O62•24 H2O). Romanelli, G.P., Bennardi, D.O., Autino, J.C., Baronetti, G.T., Thomas, H.J. E-Journal of Chemistry 5 (3) (2008) 641-647.

Efficient Microwave Solvent-Free Synthesis of Flavones, Chromones,Coumarins and Dihydrocoumarins. Bennardi, D. M. Ruiz, G. P. Romanelli, G. T. Baronetti, H. J. Thomas and J.C. Autino Letters in Organic Chemistry, 2008, 5, 607-615.

Numerical Expressions for Viscosity, Surface Tension and Density of Biodiesel: Analysis and Experimental Validation. Blangino, A. F. Riverós, S. D. Romano. Physics & Chemistry of Liquids, 46(5) 527 – 548, 2008.

Electric properties of biodiesel in the range from 20 Hz to 20 MHz. Comparison with diesel fossil fuel. E. Gonzalez Prieto, P. A. Sorichetti, S. D. Romano. Int. J. Hydrogen Energy, 33, 3531 – 3537, 2008.

Diseño de Observadores en modos cuasi-deslizantes vía LMIs. Fraguío, J. Mancilla, A. Zanini. Revista Iberoamericana de Automatización e Informática Industrial – ISSN 1697-7912. Vol 5 Nro 3 Julio 2008 – pp 54-62.

Theoretical study of the influence of cation vacancies on catalytic properties of vanadium antimonite. Messina , A. Juan , S. Larrondo , B. Irigoyen , N. Amadeo. Applied Surface Science 254 (2008) 5837-5843.

A kinetic study of ethanol steam reforming using a nickel based catalyst. Mas, M.L: Bergamini, G. Baronetti, N. Amadeo, M. Laborde. Topic in Catálisis. 5 (2008) 39-48.

In situ modification of activated carbons developed from a native invasive wood on  removal of trace toxic metals from wastewater. Jorge de Celis, Norma Amadeo, Ana L Cukerman. Journal of Hazardous Materials, 161 (2009) 217-223.

Correlations between electrical properties and flash point with methanol content in biodiesel. S. D. Romano, P. A. Sorichetti. Chemical Physics Research Journal, 3(2/3) 259 – 268, 2009.

Oxidative dehydrogenation of ethilbencene to styrene on activated carbons derived from native woods as catalyst. de Celis, S. Villaverde, A. Cukierman, N. Amadeo. Latin American Applied Research 39 (2009) 165-171.

Catalytic performance of a copper–promoted CeO2 catalyst in the CO oxidation: Influence of the operating variables and kinetic study. Schönbrod, F. Mariño, G. Baronetti, M. Laborde. Int. J. Hydrogen Energy, 34 (2009) 4021–4028.

Catalizadores a base de cobre y cerio para la reacción de oxidación preferencial de monóxido de carbono (COPROX). Fernando Mariño, Máximo Moreno, Betina Schönbrod, Graciela Baronetti y Miguel Laborde. Anales de la Academia Nacional de Ciencias Exactas, Físicas y Naturales de Buenos Aires, 61 (2009) 105-119.

Comparación de Estrategias de Control en Sistemas Multivariables Acoplados. Escudé, A. Zanini.RPIC 2009 Rosario Argentina. Septiembre 2009. ISBN 9506553402.

Modelado numérico y analítico de la distribución de tiempos de residencia en un sistema de reactores UV/ozono y lecho fijo. Hanela, A. Zanini, J. Durán. RPIC 2009 Rosario Argentina. Septiembre 2009. ISBN 9506553402.

Ni (II) Mg (II) Al (III) catalyst for hydrogen production from ethanol steam reforming: Influence of activation treatment. Adriana Romero, Matias Jobbagy, Miguel Laborde, Graciela Baronetti, Norma Amadeo. Catalysis Today 149 (2010) 407-412.

Thermodynamic analysis of glycerol steam reforming. María Laura Dieuzeide, Norma E. Amadeo. Chemical Engineering Technology 33 (2010) 89-96.

The influence of Mg on the carbon adsorption on  Ni(100). A DFT study. Hernan Milberg, Alfredo Juan, Norma Amadeo, Beatriz Irigoyen. Journal of Molecular Catalysis A . Chemical . 315, 2 (2010) 171-177.

Mechanism of CO oxidation over CuO/CeO2 catalysts. Moreno, Máximo; Bergamini Lorena; Baronetti, Graciela; Laborde, Miguel; Mariño, Fernando. Int.  J. Hydrogen Energy 35 (2010) 5918-24.

A theoretical–experimental study of Wells-Dawson phospho-tungstic heteropolyacid: An explanation of the pseudoliquid or surface-type behaviour “.Jorge Sambeth, Gustavo Romanelli, Juan C. Autino, Horacio J. Thomas, Graciela T. Baronetti. Applied Catalysis A: General, Volume 378, Issue 1 (2010) 114-118.

An Efficient One-Step Hantzsch Multicomponent Synthesis of 1,4-Dihydropyridines Via a Wells-Dawson Heteropolyacid Catalyst Under Solvent-Free Conditions”. G. Sathicq, G. P. Romanelli, A. Ponzinibbio, G. T. Baronetti and H. J. Thomas. Letters in Organic Chemistry, 7 (2010) 511-518.

Price determination for hydrogen produced from bio-ethanol in Argentina. Gregorini, D. Pasquevich, M. Laborde. Int. J. Hydrogen Energy, 35 (2010) 5844-5848.

Calculation of multiplicity of steady states in a catalyst pellet by homotopic continuation method. Giunta, Pablo, Amadeo, Norma; Laborde, Miguel; Bergamini, Maria. AIChE Journal,  57, 2 (2011) 473-481.

Ethanol steam reforming over Rh(1%)MgAl2O4/Al2O3 . A kinetic study. Cecilia Graschinsky, Miguel Laborde, Norma Amadeo, Anthony Le Valant, Nicolas Bion, Florence Epron, Daniel Duprez. Ind.Eng.Chem.Res. 49, 24 (2010), 12383-12389.

Wells–Dawson heteropolyacid as reusable catalyst for sustainable synthesis of flavones. Daniel O. Bennardi, Gustavo P. Romanellia, Ángel G. Sathicq, Juan C. Autino, Graciela T. Baronetti, Horacio J. Thomas. Applied Catalysis A: General 404 (2011) 68– 73.

Influence of the calcination temperature on the structure and reducibility of nanoceria obtained from crystalline Ce(OH)CO3 precursor.  Eduardo Poggio, Matías Jobbágy, Máximo Moreno, Miguel Laborde, Fernando Mariño, Graciela Baronetti. Int. J. Hydrogen Energy 36 (24) (2011) 15899-905.

Solvent-free synthesis of functionalized pyridine derivatives using Wells-Dawson heteropolyacid as catalyst. Laura M. Sanchez , Ángel G. Sathicq, Jorge L. Jios, Graciela T. Baronetti, Horacio J. Thomas, Gustavo P. Romanelli. Tetrahedron Letters 52 (2011) 4412–4416.

A First-Principles Modeling of Ni Interactions on CeO2-ZrO2 Mixed Oxide Solid Solutions. Cova, D. García Pintos, A. Juan, B. Irigoyen. Phys. Chem. C. American Chemical Society, 115 (2011) 7456-7465.

Estudio teórico de las interacciones del azufre sobre las superficies CeO2(111) y Rh-CeO2(111). Eugenio Russmann, A. Juan, M.G. González, B. Irigoyen. Avances en Ciencias e Ingeniería, ACI 2011, 2(3), 101 - 110.

Diseño y Control de un Sistema de Barra y Bola Utilizando Visión Artificial. Ezequiel Pecker Marcosig, Aníbal Zanini .RPIC 2011 – Oro Verde – Septiembre 2011.

Reconstrucción 3D Basada en Modelo. Ezequiel Ansaldi, Aníbal Zanini, Adrián Orellana. RPIC 2011 – Oro Verde – Septiembre 2011.

Libro Blanco del Control Automático en la Industria de la Caña de Azúcar. Capítulo de Cogeneración. Editor: Programa Iberoamericano de Ciencia y Tecnología para el Desarrollo (CYTED). ISBN: 978-84-614-8008-1 – Abril 2011.

Bio-ethanol steam reforming on Ni based catalyst. Kinetic study. Llera, V.Mas, L. Bergamini, M. Laborde, N. Amadeo. Chem. Eng. Sci. 71 (2012) 356-366.

Thermodynamic analysis of hydrogen production by autothermal reforming of ethanol. Cecilia Graschinsky, Pablo Giunta, Miguel Laborde, Norma Amadeo. Int. J. Hydrogen Energy , 37(13) (2012) 10118-10124.

Steam reforming of glycerol over Ni/Mg/γAl2O3 catalyst. Effect of calcinations temperature. M.L.Dieuzeide, V. Iannibelli, M. Jobbagy, N. Amadeo.  Int. J. Hydrogen Energy  37 (2012) 14926-14930.

COPROX Fixed Bed Reactor. Temperature control schemes. Pablo Giunta, Máximo Moreno, Fernando Mariño, Norma Amadeo, Miguel Laborde. Chem. Eng. and Technology, 35(6)(2012)1055-106.

Catalytic upgrading of levulinic acid to ethyl levulinate using reusable silica-included Wells-Dawson heteropolyacid as catalyst”. Pasquale, G., Vázquez, P., Romanelli, G., Baronetti, G. Catalysis Communications 18 (2012) 115-120.

Efficient and suitable preparation of N-sulfonyl-1,2,3,4- tetrahydroisoquinolines and ring analogues using recyclable H6P2W18O62•24H2O/SiO2 catalyst. Pasquale, G., Ruiz, D., Autino, J., Baronetti, G., Thomas, H., Romanelli, G. Comptes Rendus Chimie 15 (9) (2012) 758-763.

Adsorption of ammonia on vandium-antimony mixed oxides. Seitz, E. Germán, A. Juan, B. Irigoyen. Applied Surface Science. Elsevier 2012, 258, 3617-3623.

DFT study of H2 adsorption on Pd-decorated single walled carbon nanotubes with C-vacancies. López-Corral, J. de Celis, A. Juan, B. Irigoyen. Int.  J. Hydrogen Energy. 2012, 37, 10156-10164.

Oxygen vacancy formation on the Ni/Ce0.75Zr0.25O2(111) surface. A DFT+U study. García Pintos, A. Juan, B. Irigoyen. Int. J. Hydrogen Energy 2012, 37, 14937-14944.

Estudio de Factibilidad de la Producción de Biodiesel en Reactores Tanque Agitado Continuo de Laboratorio.D. Duarte Vera, E. O. Acosta, S. D. Romano. Revista Tecnología y Ciencia, UTN , 20, 30 – 34, 2012.

Uso de agua en la purificación de biodiesel: Optimización mediante el control de propiedades eléctricas de efluentes”, P. A. Sorichetti,  S. D. Romano. AUGMDOMUS, pp. 159 - 168, Vol. 4, 2012.

Water Consumption in Biodiesel Production: Optimization through Measurement of Electrical Properties. A. Sorichetti, S. D. Romano. Environmental Research Journal, 6(3) 231 – 240, 2012.

Electrical properties of mixtures of fatty acid methyl esters from different vegetable oils. Corach, P.A. Sorichetti, S.D. Romano. Int. J. Hydrogen Energy, 37(19) 14735 – 14739, 2012.

ARMA Model Based GPC . Zhao, Yuchen, Aníbal Zanini.Proceedings of the Int. Conf. on Integrated Modeling and Analysis in Applied Control and Automation, IMAACA 2012 - ISBN 978-88-97999-12 – Septiembre 2012 – Viena – Austria.

Artificial Vision as a Position Sensing Method for a Ball and Beam System. Ezequiel Pecker Marcosig, Aníbal Zanini. IEEE Conference on Computational Engineering and Scientific Applications – Abril 2012 – Santiago de Chile.

Optimization of the pretreatment of Prosopis nigra Sawdust for the Production of fermentable sugars. P. Dagnino, E. R. Chamorro, S. D. Romano, F. E. Felissia, M. C. Area. BioResources,  8(1) 499 – 514, 2013.

Optimization of the acid pretreatment of rice hulls to obtain fermentable sugars for bioethanol production. P. Dagnino, E. R. Chamorro, S. D. Romano, F. E. Felissia, M. C. Area. Industrial Crops and Products, 42, 363 -368, 2013.